TRANSIENT SPECTROSCOPY OF TETRAPHENYLPORPHYRINS

$155,764P41FY2001RRNIH

University Of Pennsylvania, Philadelphia PA

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Abstract

As an adjunct to our previous studies of transient absorption and resonance Raman studies on Cu tetraphenyl porphyrins (CuTPP), we are interested in the spectroscopic properties of Ni2+ and Ru2+ substituted porphyrins, where the substituents are expected to alter the charge density on the porphyrin ring structure and hence the charge transfer and metal centered excited states.

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